N,N-Dimethyl-4-[(E)-2-(3,6,7-tribromo-9-butyl-9H-carbazol-2-yl)ethenyl]aniline

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N,N-Dimethyl-4-[(E)-2-(3,6,7-tribromo-9-butyl-9H-carbazol-2-yl)ethen­yl]aniline

In the title mol-ecule, C(26)H(25)Br(3)N(2), a dihedral angle of 6.15 (10)° is present between the carbazole and benzene ring systems with an E conformation about the C=C bond [1.335 (4) Å]. The butyl group is almost perpendicular to the carbazole plane [C-N-C-C torsion angle = -98.7 (3)°]. In the crystal, supra-molecular double chains along [-7,18,-16] are formed via C-H⋯Br and π-π inter-actio...

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N-[2-(9H-Carbazol-9-yl)eth­yl]-4-(methyl­sulfon­yl)aniline

In the title mol-ecule, C21H20N2O2S, the dihedral angle between the mean plane of the carbazole ring system [maximum deviation = 0.021 (4) Å] and the benzene ring is 80.15 (6)°. In the crystal, mol-ecules are linked by N-H⋯O and weak C-H⋯O hydrogen bonds into a C(8) chain along [001].

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Crystal structure of 9-butyl-3-(9-butyl-9H-carbazol-3-yl)-9H-carbazole

In the title carbazole derivative, C32H32N2, the mol-ecule resides on a crystallographic twofold axis, which runs through the central C-C bond. The carbazole ring system is almost planar, with a maximum deviation of 0.041 (1) Å for one of the ring-junction C atoms. The crystal packing is stabilized by C-H⋯π inter-actions only, which form a C(7) chain-like arrangement along [110] in the unit cell.

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9-{4-[(E)-2-(4,6-Dimethyl-1,3,5-triazin-2-yl)ethen­yl]phen­yl}-9H-carbazole

In the crystal structure of the title compound, C(25)H(20)N(4), the triazinyl ring is nearly coplanar with the planar (r.m.s. deviation = 0.028 Å) phenyl-ethenyl unit, the twist being only 5.8 (2)°; however, the planar carbazolyl unit (r.m.s. deviation = 0.008 Å) is twisted by 47.8 (1)° with respect to the phenyl-ethenyl unit. The nonplanar nature of the mol-ecule explains the phenomenon of lig...

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(E)-3-(9-Ethyl-9H-carbazol-3-yl)-1-(2-meth­oxy­phen­yl)prop-2-en-1-one

In the title mol-ecule, C24H21NO2, the dihedral angle between the carbazole ring system [with a maximum deviation of 0.052 (2) Å] and the benzene ring is 38.6 (1)°. In the crystal, weak bifurcated (C-H)2⋯O hydrogen bonds link the mol-ecules into chains along [100].

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812011336